News

November 2015

Suitable materials for pressure vessels

Preface The pressure vessel design includes a variety of stresses- longitudinal and hoop stresses are developed by internal pressure, different bending stresses caused by bending moment, wind loads and seismic loads, compressive and tensile stresses because of dead weight of platform and vessel contents, peak stress by irregularities particularly in localized regions and stresses by thermal gradient. Hence a designer needs to consider the entire probable loads and moments on a pressure vessel. The allowable pressure that is based on service temperature, lowest tensile strength of the flange material and bolt material are considered following the design stress. The thermal stresses are crucial for pressure vessel designing. Stress in pressure vessels A pressure vessel is categorized as thin, if ratio of mean radium and wall thickness is above 10. Stresses produced in thin pressure vessels because of internal pressure are called as membrane stresses. A designer needs to design a pressure vessel by also considering the failure factors. The stress theory states the failure in brittle materials however it is not precise always particularly for ductile alloys. Traditionally cast iron was utilized for a pressure vessel however modern vessel codes demand using ductile materials. At the cryogenic limits up to -250oC, stainless steel grades are used, at normal temperature limits up to 400oC, carbon steels are employed and for temperature limits ranging from 600oC to 900oC or above this limit, stainless steel grades are used. Often Inconel grades are used in the production of pressure vessels. The peak stresses at irregularities result in fatigue condition because of stress escalation in high and localized regions. These stresses causes fatigue failures. Various stresses paired with fatigue loads and because of seismic shock loads, intense safety protocols are followed by designers while prototyping the pressure vessel. Non-damaging inspection of pressure vessels exposed to large internal pressures, wind loads and seismic stresses are principle attributes to find the internal flaws in the vessel material. The non-damaging methods are used that involve radiography, ultrasonic and liquid penetrant and magnetic particle technique. In these, radiography is a precise and consistent method. It should be remembered that additional membrane stresses are resulted by internal pressure, the extensive localized stresses are resulted by irregularities and bending stresses resulted by wind pressure. However these are permitted with incorporation of extreme safety. The key factors are included in the selection of construction materials for pressure vessels to avoid damage during the service. This post describes the essential design factors, common materials and properties of these materials. Design attributes Service temperature and pressure, application condition, cost, design life, reliability and safety.

pressure vessel Inconel, Monel, Hastelloy Grades

Service temperature and pressure limit the material selection widely influence the corrosion rates, The influences of service temperature limits is analyzed through severely decreased strength, metallurgy and corrosion resistance characteristic. For example, carbon steel can serve up to 800oF. Above this limit, the strength of carbon steel reduces considerably and carbon steel may be embrittled by graphitization. Corrosion rates rapidly increase with increase in temperature. For instance, carbon steel offers service up to 550oF when directly subjected to sour conditions without any security, the corrosion rates increase at higher temperatures. Influence of service pressure- Affects the material’s stability in the service condition such as hydrogen attack of steels in the high pressure and elevated temperature H2S service. Service conditions – before subjecting for use, the considered factors are vessel materials, temperature and pressure, contaminants, physical state and flow rate. The material selection for pressure vessels is based on the corrosion rate and other severe damaging mechanisms that include stress corrosion cracking and hydrogen embrittlement. The corrosion rate data helps in determining whether the chosen material was appropriate by expected corrosion and lab tests. Get advice from the material manufacturer for special recommendations. Price- Purpose is to choose an economical and reliable material that can operate longer within the minimum cost. If stainless steel or other high alloyed material is desired, carbon or low alloy steel clad is used with a thick electrodepositing of high alloy material. Clad plate is economical for vessel thickness below ½ inch. It is also sensitive to produce the corrosion cracking as compare to rigid alloy. The commonly used cladding materials are not practical to produce solid wall construction due to difficulty in producing reliable welds. Possibility and result of failure should be taken into account. The failure cases are determined from the material experience in the past experiments and shutdown frequency. Typical pressure vessel material application standards Carbon steel Easily available and producible. Affordable material selection with 1/8 – ¼ inch corrosion allowance. Small iron content with 1% manganese and 0.35 % carbon. Larger carbon content reduces weldability. But carbon steels are sensitive to brittle fracture at standard ambient temperatures. Carbon steel is corroded by hydrogen attack at the high temperatures in high pressure hydrogen. Production of graphite, specifically in weld heat affected regions from decomposition of iron carbides. Graphitized steel cannot withstand even small pressure or loads. Welded carbon steel can serve below 800oF. Welded or cold process carbon steel is also prone to stress corrosion cracking in caustic, nitrate, carbonate, amine solutions and in anhydrous ammonia. Stress relief is needed to prevent damages. High strength steel in aqueous solutions of hydrogen sulfide (H2S) cause rapid non-ductile damages. Monitoring highest strength and hardness is required to avoid damage. Post weld heat processing also helps in preventing cracking. Hydrogen Induced Cracking- Low strength carbon steels are sensitive to hydrogen induced cracking in wet solutions of H2S. For example blistering. Post-weld heat processing is helpful to secure carbon steel from such cracking. Such steels are not commonly used. Stainless steel Steel types made of iron and chromium containing minimum 12% chromium and bal. nickel come in the stainless steel 300 series. For example stainless steel 304. Molybdenum, titanium and columbium are included for special objectives. The stainless steels are categorized on the base of their microstructure such as Austenitic and Ferritic. Duplex stainless steels offer enhanced resistance to chloride induced stress corrosion cracking. This attack can be prevented as-

Avoid choosing rigid wall austenitic stainless steel for warm and aqueous chloride services such as when need stainless steel, clad steel is preferred.
Stress relieved vessels produced of solid austenitic stainless steel where alternative is not available.

Steels for Sulfur Derived Acids Sulfur derived acids cause polythionic acid based stress corrosion cracking. Unlike chloride induced stress corrosion racking, the steel is sensitized with chromium carbide precipitates throughout the grain boundaries prior the occurrence of polythionic acid based stress corrosion cracking. Sensitization is caused from subjecting the stainless steel equipment to temperatures up to 700oF. For standard carbon steels such as stainless steel type 304 and stainless steel grade 316, they are sensitized while welding. The sulfurous and polythionic acids are not found in process equipments during services. These are generally produced during shutdowns by oxidation of iron sulfide scale in moisture and oxygen. In the flue gas condenser, polythionic acid based SCC can be prevented by avoiding contact between sensitized austenitic stainless steels and sulfur based acids. Steel grade 304 is sensitized rapidly above 700oF. The weld heating is sufficient to sensitize the heat affected region. Additional low carbon steel grades such as stainless steel 304l or 316l are not sensitized while welding and it can be done through prolong exposure up to 700oF. Steel grade 321 is chemically stabilized to reduce sensitization. Polythionic acid cracking is inhibited by using chemically stabilized or other mild carbon steel types and preventing deteriorating heat treatments. Stainless steel for use above 400oF The high chromium based stainless steels produce sigma phase at high temperature and are attacked by embrittlement at lower temperature limits. Sigma phase is hard, fragile and non-magnetic in nature and its chemistry is based on an alloy in which it is produced. It doesn’t influence the high temperature characteristics of steel however may reduce its ductility at low temperatures due to which the system may be damaged while commencing or shutting down. Stainless steel grades with above 13%chromium content that are ferritic and martensitic in nature are extremely prone to wide sigma phase production. The austenitic steel grades are not much sensitive due to presence of high nickel magnitude however can produce unwanted magnitudes of sigma phase when held between 1000oF to 1500of for prolong periods. Specifically very sensitive austenitic grades for example casting and welds may produce extensive embritllement within less time at the limits of 1200oF to 1300oF. The duplex steel grades are sensitive to sigma embrittlement that is limited by decreasing ferritic magnitude in stainless steel grades. The Super duplex stainless steel 2205 is limited to 650oF highest operation temperature to prevent embrittlement. Sulfide stress cracking- Martensitic grades are sensitive. The welds are hardly softened through heat processing and hence are sensitive to fracture. The cracking can be inhibited by limiting the weld strength and hardness. The commonly used materials are: Nickel Alloys Monel, Inconel grades, Incoloy and Hastelloy alloys are utilized for special applications and often as cladded. Few nickel alloys offer suitable resistance to chloride solutions when stainless steel grades do not offer adequate performance. Fabricating and weldabiltity are suitable with required safety measures. The desired characteristics and temperature constraints of commonly used pressure vessel materials are: Highest temperatures of standard pressure vessel materials, in oF

	Carbon steel	C-1/2 Molybdenum	1 ½ Chromium-1 Molybdenum	2 ¼ Chromium-1 Molybdenum	12 Chromium	18chromium – 8Nickel (Grade 304)
Strength, 3000 psi	990 oF	1075 oF	1135 oF	1150 oF	1100 oF	1275 oF
Oxidation (10 mpy loss)	1025 oF	1025 oF	1050 oF	1100 oF	1350 oF	1600 oF
Graphitization (welded)	800 oF	850 oF	Not applicable	Not applicable	Not applicable	Not applicable
885 embrittlement	N/C	Not applicable	Not applicable	Not applicable	775 to 950 oF	Not applicable
Sigma embrittlement	Not applicable	Not applicable	Not applicable	Not applicable	Not applicable	1100 – 1700 oF
Hardening on cooling	1330 oF	1330 oF	1375 oF	1425 oF	1450 oF	Not applicable
Carbide precipitation	Not applicable	Not applicable	Not applicable	Not applicable	Not applicable	850 to 1550 oF
Hydrogen attack H_2pp (750 psi)	500 oF	500 oF	1000 oF	1100 oF	Not applicable	Not applicable
Caustic stress corrosion cracking	140 oF	140 oF	140 oF	140 oF	140 oF	140 oF
Chloride stress corrosion cracking	Not applicable	Not applicable	Not applicable	Not applicable	Not applicable	140 oF
Sulfide stress cracking	Sensitive if yield strength is above 90 ksi	Sensitive if yield strength is above 90 ksi	Sensitive if yield strength is above 90 ksi	Sensitive if yield strength is above 90 ksi	Sensitive if yield strength is above 90 ksi	Not applicable

According to AD specifications base metals and filter metals should be individually validated for the production of pressure vessels to withstand various thermal shocks and formed from nickel alloys that keep their mechanical characteristics at the high temperatures. Inconel alloy 718 was discovered, unlike to the experience received by sheet metal producers, could not be subjected for use in the age hardened conditions due to the development of brittle lave phases in the weld metal. The experience received with non-age hardening alloy 625 was satisfactory, but as it was discovered that alloy 625 can be employed with complications for producing the shell. An experience is earned with TIG and on conditions under which alloys such as Inconel 625 and 718 are welded. Heanjia Super-Metals is specialized in the production of essential materials such as Inconel, Monel, Hastelloy and carbon & stainless steel and other materials for the production of custom tanks and pressure vessels for the industrial and commercial units. The industrial facility is capable to manage intensive fabrication of alloys that are used in the production of heavy duty vessels up to 60 tons, 110 ft and 10 ft in diameter. The alloys are chemical and corrosion resistant materials that offer prolong performance.